The first an easiest I know is flat 5 sub.
Everything can be seen as II V I progressions, even if at first it doesn't appear to be, deep down everything can be made into a II V I.
Now.... a flat 5 sub.... takes the V7 chord, goes a b5 from there to....
II Dmin7
V G7
I CMaj7
II Dmin7
(V) Db7
I CMaj7
Nice chromatic run yeah? .... Well the Db7 is a "secondary dominant" substitution for the G7. Looking at the notes they are similar enough to be used.
.....
Another is "plurals" which I never really "got".... II subs for III, IV subs for VI or something like that.... Was one of those "memorise this" things which isn't how I learn, so didn't work for me.
.....
Instead I went off to derive my own little method..... Which I can't really remember the details of, but remember the outcome....
I did 2 layers of b5 substitutions looking at all the notes in the chords given. If I did too many layers I'd end up with the chromatic scale, so I pulled back 1 layer from there to have something non-chromatic to work with. Which resulted in the "altered scale"... um.... it has a bunch of names.... It's a symetrical scale....
STSTSTSTSTST etc...
So lets look at E Maj on a guitar....
F,Gb,Ab,A,B,C,D,Eb,F
S T S T S T S T
Now the easiest way to hear this is....
Play E Maj on the guitar, at open position so most of the notes are open strings.... Now slide the chord up in that classic flamenco style where you're playing F Maj with open strings ringing E...... Do the same up the neck in the altered scale, 1 fret, 2 frets, 1 fret, 2 frets......
You'll notice they all fit fine with the open strings, and how as you approach the octave they have quite a lot of tension built while still spelling basically the same sound.
You can uses these as V chords.... Think pipe organ and Amen..... Now instead of doing a straight V->I.... build it thru some of these subs.... you can hear how it all remains pretty much inside the V as secondary dominants.
That's my little way of thinging bout it.... I don't modulate as much as I should, a few little tricks like this look after me fairly well.
-Ben